4.7 Article

An I-doped (BiO)(2)CO3 nanosheets-wrapped carbon cloth for highly efficient separation of oil-in-water emulsions

Journal

JOURNAL OF MEMBRANE SCIENCE
Volume 567, Issue -, Pages 209-215

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2018.09.043

Keywords

Bismuth subcarbonate; Carbon cloth; Superhydrophilicity; Oil/water emulsion separation; Photoresponsive wettability

Funding

  1. National Key R&D Program of China [2017YFC0210901, 2017YFC0210906]
  2. National Natural Science Foundation of China [51573122, 21722607, 21776190]
  3. Natural Science Foundation of the Jiangsu Higher Education Institutions of China [17KJA430014, 17KJA150009]
  4. Science and Technology Program for Social Development of Jiangsu [BE2015637]
  5. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

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(BiO)(2)CO3 was introduced on the surface of a carbon cloth through a facile hydrothermal route; the carbon cloth surface possessed superamphilicity in air, superhydrophobicity under oil with a contact angle of 156 degrees and superoleophobicity under water with a contact angle of 154 degrees. This material showed a high separation efficiency of 99.91% for emulsifier-stabilized emulsions. We conducted recycling experiments and abrasion experiments to study the physical properties and stability of the material. The materials had good recyclability and abrasion resistance. The material also displayed photoresponsive wettability; and a possible explanation was proposed.

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