Journal
JOURNAL OF MEMBRANE SCIENCE
Volume 566, Issue -, Pages 223-230Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2018.08.051
Keywords
Solvent resistant nanofiltration; Organic solvent nanofiltration; PVDF; Crosslinking; Solvent tolerant nanofiltration
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Funding
- Belgian Federal Government (IAP FS2)
- KU Leuven [C16/17/005, IOF-KP 13/004]
- IWT-STW (SBO-Nanomexico)
- IWT
- FWO
- Dep. Materials Engineering, KU Leuven
- Hercules fund [AKUL/13/19]
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Crosslinked poly(vinylidene difluoride) (PVDF) nanofiltration membranes were prepared and tested for solvent resistant nanofiltration (SRNF) and solvent tolerant nanofiltration (STNF, i.e. in solvent/water media) applications. The performance of the membranes was assessed by filtering ethanol (EtOH), iso-propanol (iPrOH), acetonitrile (ACN), dimethylformamide (DMF) or toluene (Tol) solutions containing Rose Bengal (RB), a 1017 Da solute. During these consecutive filtrations, the membranes displayed a solvent activation effect which was characterised by TEM, ATR-FTIR and via intermediate EtOH filtrations. This solvent activation resulted in a more permeable membrane (by a factor of 11), without loss in retention. Drying the membranes from MeOH resulted in a further increase of the RB retention in ACN and Tol to 98%. The stability of the membranes was characterised using SEM, weight loss analysis and ATR-FTIR. In STNF, a 99% RB retention was achieved from a 1:4 DMF/water mixture.
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