Journal
JOURNAL OF MEMBRANE SCIENCE
Volume 472, Issue -, Pages 133-140Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2014.08.049
Keywords
Porous polymer electrolyte; Sandwich-like architecture; Electrolyte uptake; Safety; Lithium ion batteries
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Funding
- Commonwealth of Australia through the Automotive Australia Cooperative Research Centre (AutoCRC)
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Porous polymer membrane with a sandwich-like architecture has been prepared by coating poly(methyl methacrylate) (PMMA) on poly(vinylidene fluoride-co-hexafluoropylene) (PVDF-HFP) porous membranes. Field emission scanning electron microscopy analysis identified that the PMMA/PVDF-HFP porous polymer membrane consists of the stacking of several porous layers with one layer of large pores in the middle of the membrane. This unique sandwich like structure provides large porosity and good affinity towards a liquid organic electrolyte, leading to a high electrolyte uptake of 342 wt%, excellent electrolyte retention, and enhanced tolerance towards high temperature and fire. The gel polymer electrolyte membrane achieved a high ionic conductivity of 1.31 mS cm(-1) with similar activation energy as the conventional Celgard 2400 separator in liquid electrolyte. The porous polymer electrolyte membrane also has an outstanding thermal and electrochemical stability. When applied in lithium ion batteries with LiFePO4 cathode and lithium metal anode, the PMMA/PVDF-HFP electrolyte membrane demonstrated high discharge capacity, enhanced high rate capability, and extended cycle life. The PMMA/PVDF-HFP porous polymer membrane could be employed as an integrated separator and electrolyte for lithium ion batteries with high safety. (C) 2014 Elsevier B.V. All rights reserved.
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