Low-pressure membrane filtration of secondary effluent in water reuse: Pre-treatment for fouling reduction

Fouling in the low-pressure membrane filtration of secondary effluent for water reuse can be severe due to the complex nature of the components in the water. Pre-filtration, coagulation and anion exchange resin were investigated as pre-treatments for reducing fouling of microfiltration (MF) and ultrafiltration (UF) membranes in the treatment of activated sludge-lagoon effluent. The key fouling components were determined using several analytical techniques to detect differences in the organic components between the feed and permeate. Pre-filtration (1.5 mu m) enhanced the permeate flux for MF by removing particulates, but had little effect for UF. Marked flux improvement was obtained by coagulation pre-treatment at 5 mg L-1 Al3+ with internal membrane fouling being substantially alleviated. Anion exchange resin removed >50% of effluent organic matter but did not improve the flux or reduce irreversible membrane fouling. These results, together with detailed organic compositional analyses, showed that the very high-molecular weight organic materials (40-70 kDa) comprised of hydrophilic components such as soluble microbial products, and protein-like extracellular matter were the major cause of membrane fouling. (C) 2008 Elsevier B.V. All rights reserved.