4.7 Article

Electrochemical corrosion behavior of 2A02 Al alloy under an accelerated simulation marine atmospheric environment

Journal

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
Volume 35, Issue 4, Pages 651-659

Publisher

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2018.09.060

Keywords

Thin electrolyte layers; Atmospheric corrosion; 2A02 Al alloy; EIS

Funding

  1. National Natural Science Fund of China [51622106, 5167010950]
  2. National Key Basic Research and Development Plan of China [2014CB643303]
  3. International S& T Cooperation Program of China (ISTCP) [2014DFR50560]

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The corrosion behavior of 2A02 Al alloy under simulated marine atmospheric environment has been studied using mass-gain, scanning electron microscope/energy dispersive spectroscopy (SEM/EDS), laser scanning confocal microscopy, X-ray diffraction spectroscopy and localized electrochemical methods. The results demonstrate that the relationship between the corrosion induced mass-gain and the corrosion time is in accordance with the power rule. The mass-gain increases gradually during the corrosion time, while the corrosion rate decreases. With ongoing of the corrosion, corrosion products film changed from a porous to a compact structure. The various spectroscopic data show that the corrosion products films composed mainly of Al(OH)(3), Al2O3 and AlCl3. The electrochemical corrosion behavior of the 2A02 Al alloy was studied by electrochemical impedance spectroscopy (EIS). (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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