Journal
JOURNAL OF MATERIALS SCIENCE
Volume 50, Issue 4, Pages 1783-1793Publisher
SPRINGER
DOI: 10.1007/s10853-014-8741-y
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Funding
- World Premier International Research Center Initiative (WPI), MEXT, Japan
- Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST MISiS [K2-2014-013]
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In the present work, we discuss the glass-forming ability of various binary alloys in which the glassy phase was not formed even by melt spinning technique with high cooling rate of the melt up to 1 MK/s (some consisted of partly glassy phase), though by commonly accepted guidelines, these alloys could be as good glass-formers as many other binary glasses. The alloys studied belong to binary systems with multiple eutectics; the constituent elements have a negative enthalpy of mixing, and a significant variability of atomic size differences is observed from system to system. The results indicate the necessity of taking into account simultaneously various factors influencing the glass-forming ability including melt fragility.
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