Journal
JOURNAL OF MATERIALS SCIENCE
Volume 46, Issue 20, Pages 6545-6555Publisher
SPRINGER
DOI: 10.1007/s10853-011-5601-x
Keywords
-
Categories
Funding
- Czech Science Foundation [GAP104/10/2344, GA103/09/1748, MSM 6046137302]
Ask authors/readers for more resources
The process of alkali activation of fly ash and metakaolin is examined in the view of micromechanics. Elasticity is predicted via semi-analytical homogenization methods, using a combination of intrinsic elastic properties obtained from nanoindentation, evolving volume fractions and percolation theory. A new quantitative model for volume fraction is formulated, distinguishing the evolution of unreacted aluminosilicate material, solid gel particles of N-A-S-H gel, and open porosity, which is partially filled with the activator. The stiffening of N-A-S-H gel is modeled by increasing the fraction of solid gel particles. Their packing density and intrinsic elasticity differ in N-A-S-H gels synthesized from both activated materials. Percolation theory helps to address the quasi-solid transition at early ages and explains a long setting time and the beneficial effect of thermal curing. The low ability of N-A-S-H gel to bind water chemically explains the high porosity of Ca-deficient activated materials. Micromechanical analysis matches well the elastic experimental data during the activation and elucidates important stages in the formation of the microstructure.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available