High-Strength Geopolymer Using Fine High-Calcium Fly Ash

In this paper, the synthesis of high-strength geopolymer using fine high-calcium fly ash was studied. The effect of fineness of fly ash on the setting time of geopolymer paste, workability, strength development, and drying shrinkage of geopolymer mortars made from classified fine high-calcium fly ash was investigated. Air-classified fly ash with three different finenesses coarse original fly ash (CFA), medium-fineness fly ash (MFA), and fine fly ash (FFA) from the Mae Moh Power Station was used for this study. The heat-cured geopolymers were activated with sodium hydroxide (NaOH) and sodium silicate. A small amount of water was incorporated for workability. The results indicate that the setting time of paste decreases with an increase in fly-ash fineness. The flow, strength, and drying-shrinkage characteristics of mortars were improved using fine fly ash. Geopolymer mortars with high 28-day compressive strength of 86.0 MPa were obtained. DOI: 10.1061/(ASCE)MT.1943-5533.0000161. (C) 2011 American Society of Civil Engineers.