Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 10, Pages 4178-4187Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm14951f
Keywords
-
Funding
- NSFC [61072014, 51103164]
- Ministry of Science and Technology of China [2011CB932304]
- Chinese Academy of Sciences
Ask authors/readers for more resources
With the rapid evolution of photovoltaic polymer materials, power conversion efficiency of polymer solar cells has been markedly improved in recent years, and is now approaching a landmark value of 10 %. This review focuses on Donor-Acceptor (D-A) photovoltaic copolymers. Starting from briefly introducing the D-A concept, the fundamental donor and acceptor units for constructing polymer photovoltaic materials are introduced and classified. By summarizing the structure-property relationships of typical photovoltaic D-A copolymers, the important design rules for such materials are highlighted. Several crucial aspects, including proper combination of D-A units, high planarity of the backbone and proper incorporation of side chains are particularly emphasized. A new D-A architecture, namely main-chain donor and side-chain acceptor is introduced and reviewed. Moreover, the role of the electron-deficient group in fine-tuning energy levels of low-bandgap D-A photovoltaic polymers is discussed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available