4.3 Article

Complete structural model for lanthanum tungstate: a chemically stable high temperature proton conductor by means of intrinsic defects

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 5, Pages 1762-1764

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm14981h

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Funding

  1. Research Council of Norway
  2. NOTUR supercomputer infrastructure in Norway

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This is the first paper reporting that lanthanum tungstate, earlier believed to be La6WO12, is in fact La28-xW4+xO54+delta, where tungsten dissolves in lanthanum sites to form a stable solid-state electrolyte, exhibiting proton conduction by hydration at intermediate temperatures.

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