Journal
PARTICULATE SCIENCE AND TECHNOLOGY
Volume 34, Issue 6, Pages 658-664Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/02726351.2015.1102188
Keywords
Adsorption; isotherm model; kinetic; methylene blue
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In this study, adsorption of methylene blue from aqueous solution onto peanut shell has been investigated. Experimental data obtained from dye adsorption have been studied by five two-parameter (Langmuir, Freundlich, Dubinin-Radushkevich, Temkin, and Frumkin) and five three-parameter (Redlich-Peterson, Sips, Toth, Radke-Prausnitz, and Koble-Corrigan) isotherm models. Eight nonlinear error functions (sum squares errors, hybrid fractional error function, Marquardt's percent standard deviation, average relative error, sum of absolute error, the coefficient of determination, nonlinear chi-square test, and standard deviation of relative errors) were examined for isotherm equations. In order to explain the adsorption kinetics fit of pseudo-first-order, pseudo-second-order, Elovich, and intraparticle kinetic models were used. The best fitting isotherm model was the Radke-Prausnitz and kinetics model was pseudo-second-order. Adsorption experiment showed that the maximum capacity of agricultural waste for methylene blue was 67.57 L.g(-1) at 25 degrees C.
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