Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 30, Pages 15153-15159Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm31439h
Keywords
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Funding
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2011-0010369, 0458-20110053]
- Joint Research Project
- Korea Research Council of Fundamental Science & Technology (KRCF)
- KIST Institutional Program [2E22873-12-020]
- E-bank Project
- National Research Council of Science & Technology (NST), Republic of Korea [Seed-10-2, 2E2334] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2011-0010369] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Different shapes of various nickel structures, including dendrite, particle and film are fabricated by electrodeposition under various conditions. The shape of nickel structures is definitely dependent on the deposition potential, leading to different electrochemical surface area and edge facets. The nickel particle which has a polycrystalline center and edge is obtained at high negative potential. On the other hand, the nickel dendrite deposited by relatively low negative potential exhibits large electrochemical surface area and a particularly active facet for hydrogen evolution reaction (HER) in alkaline water electrolysis. In fact the nickel dendrite shows the highest catalytic activity and stability for HER among the various nickel structures.
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