4.3 Article

Impact of mechanical bending on the electrochemical performance of bendable lithium batteries with paper-like free-standing V2O5-polypyrrole cathodes

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 22, Pages 11159-11165

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm16470a

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Funding

  1. Australian Research Council through the ARC Centre of Excellence for Electromaterials Science [DP0987805]

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Highly flexible, paper-like, free-standing V2O5 and V2O5-polypyrrole (PPy) films were prepared via the vacuum filtration method. The films are soft, lightweight, and mechanically robust. The electrochemical performance of the free-standing pure V2O5 electrode was improved by incorporating conducting polypyrrole. A bendable cell with a novel design was fabricated, consisting of a freestanding V2O5-PPy cathode film, gel electrolyte, and a lithium foil anode. The cell was tested under repeated bending conditions for several cycles. The results show that the battery performance of the repeatedly bent cell was similar to that of the conventional cell.

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