4.3 Article

Dodecyl sulfate-induced fast faradic process in nickel cobalt oxide-reduced graphite oxide composite material and its application for asymmetric supercapacitor device

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 43, Pages 23114-23119

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm35307e

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Funding

  1. Nanyang Technological University, Singapore
  2. NRF-Create under Nanomaterials for Energy and Water Management

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In this contribution, we report a facile preparation method of nickel cobalt oxide-reduced graphite oxide (NiCo2O4-rGO) composite material. A fast Faradic process has been realized by sodium dodecyl sulfate (SDS)-induced ultrasmall NiCo2O4 nanocrystals on rGO. As a result, this composite material gives a high specific capacitance of 1222 F g(-1) at 0.5 A g(-1) and 768 F g(-1) at 40 A g(-1), showing an outstanding rate capability. An asymmetric supercapacitor device with high energy and power densities has been successfully assembled based on NiCo2O4-rGO composite material and activated carbon. The optimized device shows a high energy density of 23.32 Wh kg(-1) at a power density of 324.9W kg(-1). In addition, this asymmetric device shows good stability towards multistage current charge-discharge cycles.

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