Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 20, Pages 10195-10199Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm15538a
Keywords
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Funding
- National Basic Research Program [2011CB808704]
- National Natural Science Foundation of China [21021062, 20931004]
- Fundamental Research Funds for the Central Universities [1114020502]
- Welch Foundation [AX-1730]
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By using an octadentate ligand tetrakis[(3,5-dicarboxyphenoxy) methyl]methane (H8L), a new microporous metal-organic framework [Cu4L(H2O)(4)](H2O)(31) (1) was solvothermally synthesized and structurally characterized. MOF 1 is built from the 4-connected square planar [Cu-2(O2CR)(4)] cluster and 8-connected cube ligand L to have a highly open framework with scu topology. It possesses permanent porosity as confirmed by N-2, H-2, C2H2, CO2 and CH4 gas adsorption measurements and exhibits high acetylene storage of 193 and 154 cm(3) g(-1) at 273 and 296 K under 1 atm, respectively.
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