Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 45, Pages 23893-23899Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm34472f
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Funding
- Alexander von Humboldt Foundation
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Hierarchical porous carbide-derived carbon monoliths (HPCDCM) were prepared by selective extraction of silicon from ordered mesoporous silicon carbide monoliths (OMSCM) through chlorination at high temperature. The OMSCM was firstly synthesized by pressure-assisted nanocasting procedure using KIT-6 silica as the hard template and polycarbosilane (PCS-800) as the preceramic precursor. The OMSCM showed cubic ordered mesoporous structure with specific surface area of over 600 m(2) g(-1). After the chlorination, the resulting HPCDCM demonstrated very high specific surface area (2933 m(2) g(-1)), large pore volume (2.101 cm(3) g(-1)) with large volume of micropores (0.981 cm(3) g(-1)), and narrow dual pore size distributions (micropore: 0.9 nm, and mesopore: 3.1 nm). Macropores in the micron range were observed in the HPCDCM. The mesostructural ordering was not maintained in the HPCDCM and the volume of the HPCDCM had greatly shrunk, by 21.2% compared to that of the OMSCM, but the tablet-like appearance was well retained in the HPCDCM. At -196 degrees C, the HPCDCM shows good hydrogen uptakes of 2.4 wt% and 4.4 wt% at 1 bar and 36 bar, respectively. The calculated volumetric hydrogen storage capacity is 11.6 g L-1 at 36 bar. The gravimetric hydrogen uptake capacity of the HPCDCM is comparable to, or higher than, those of previously reported ordered mesoporous carbide-derived carbon (CDC) powder and microporous CDC powder.
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