Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 6, Pages 2650-2657Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm13826c
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Funding
- National Science Foundation of China [91022021, 30890141, 21125104]
- National Basic Research Program of China [2009CB930400]
- Program for Innovative Research Team in University [IRT0911]
- Shanghai Leading Academic Discipline Project [B108]
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Phenol substituted 1,8-naphthalimide derivatives acting as a donor and an iridium(III) complex which emits orange light acting as an acceptor were synthesized to fabricate a novel white-light-emitting two-component gel. The intermolecular energy transfer between the two components plays a crucial role in providing the tuneable emission in the mixed gels. The emission of white light can be obtained by carefully tuning the ratio of the two components. These gels are ideal constituents for the design of supramolecular light-harvesting materials, which afford a novel approach to displaying information in soft materials with tuneable optical properties. Furthermore, the two-component gel can respond to cysteine with an obvious change in luminescence that is visible to the naked eye.
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