Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 24, Pages 12193-12197Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm31162c
Keywords
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Funding
- NSFC [51121091, 21133001, 61176004]
- MSTC [2007CB936201, 2011CB808702]
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Silicon is a promising anode material for lithium ion batteries because of its low discharge potential and high theoretical charge capacity (4200 mA h g(-1)). However, the poor cycle performance, which arises from the large volume change upon the insertion and extraction of lithium ions, has limited its application. Here, we introduce a composite structure of coaxial carbon-silicon-carbon nanotube arrays in a porous anodic aluminium oxide membrane as a high-capacity and long-life anode. The carbon layer can not only protect silicon from generating a solid electrolyte interphase, but can also function as the current collector. These anode materials have a high first Coulombic efficiency of 90% and high specific capacities (similar to 4000 mA h g(-1) for silicon and more than 600 mA h g(-1) for the whole anode). Significantly, using these composite structures we have obtained an area capacity of similar to 6 mA h cm(-2), which is larger than commercial graphite anode values.
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