4.3 Article

Self-templating surface-initiated polymerization: a route to synthesize conductive brushes

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 38, Pages 20179-20181

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm34480g

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Funding

  1. Polish Ministry of Science and Higher Education [IdP2011 000561]
  2. European Regional Development Fund [POIG.02.01.00-12-023/08]

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A facile self-templating approach for the synthesis of surface-grafted conjugated brushes has been introduced here. Polymeric chains containing acetylene moieties were first grafted from a gold surface and then the side groups were polymerized. After doping the obtained brushes exhibited high conductivity (10(3) S cm(-1)) in the vertical direction.

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