Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 20, Pages 10148-10151Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm15615f
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Funding
- Federal German Ministry of Economics (BMWi) [0327851B/C]
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The adsorption/desorption of up to 0.75 g of water vapour per g of the porous MOFs 3D-{M3O(X)(H2O)(2)[btc](2)center dot nH(2)O}, MIL-100 (M = Al, Fe; X OH, F, btc benzene-1,3,5-tricarboxylate, trimesate), occurs at small relative pressures of p/p(0) < 0.4 and a comparatively small hysteresis. Together with very good cycle stability, these properties render both MIL-100(Al and Fe) very suitable candidates for thermally driven heat pumps or adsorption chillers.
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