4.3 Article

In situ synthesis of magnetically recyclable graphene-supported Pd@Co core-shell nanoparticles as efficient catalysts for hydrolytic dehydrogenation of ammonia borane

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 25, Pages 12468-12470

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm32229c

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Funding

  1. Chinese Academy of Sciences
  2. National Program on Key Basic Research Project of China (973 Program) [2012CB215500]
  3. Foundation for Innovative Research Groups of the National Natural Science Foundation of China [20921002]
  4. National Natural Science Foundation of China [21101147]
  5. Jilin Province Science and Technology Development Program [20100102, 20116008]

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Graphene supported Pd@Co core-shell nanocatalysts with magnetically recyclability were synthesized via the in situ synthesis strategy utilizing the distinction in reduction potentials of the two precursors with appropriate reductant. The as-synthesized catalysts exerted satisfied catalytic activity (916 L mol(-1) min(-1)) and recycle stability for hydrolytic dehydrogenation of ammonia borane.

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