Journal
PARTICLE & PARTICLE SYSTEMS CHARACTERIZATION
Volume 33, Issue 2, Pages 110-117Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppsc.201500218
Keywords
anodes; hollow silica spheres; lithium-ion batteries; porous carbon
Funding
- National Science Foundation (NSF) [DMR-1505902]
- National Natural Science Foundation of China [51274015]
- China Scholarship Council (CSC)
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1505902] Funding Source: National Science Foundation
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Silica (SiO2) is regarded as one of the most promising anode materials for lithium-ion batteries due to the high theoretical specific capacity and extremely low cost. However, the low intrinsic electrical conductivity and the big volume change during charge/discharge cycles result in a poor electrochemical performance. Here, hollow silica spheres embedded in porous carbon (HSS-C) composites are synthesized and investigated as an anode material for lithium-ion batteries. The HSS-C composites demonstrate a high specific capacity of about 910 mA h g(-1) at a rate of 200 mA g(-1) after 150 cycles and exhibit good rate capability. The porous carbon with a large surface area and void space filled both inside and outside of the hollow silica spheres acts as an excellent conductive layer to enhance the overall conductivity of the electrode, shortens the diffusion path length for the transport of lithium ions, and also buffers the volume change accompanied with lithium-ion insertion/extraction processes.
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