Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 34, Pages 17671-17676Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm32164e
Keywords
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Funding
- Innovation Program of Shanghai Municipal Education Commission [12ZZ006]
- Shanghai Rising-Star Program [10QA1400300]
- National Natural Science Foundation of China [50903019, 21001028, 51133001, 21074023]
- Foundation for the Author of National Excellent Doctoral Dissertation of PR China [200943]
- Doctoral Program of Higher Education of China [200802461085, 20110071130002]
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This paper presents a simple and effective strategy to construct a UV photodetector based on ZnS hollow-spheres by oil-water interfacial self-assembly of polystyrene (PS)/ZnS colloidal nanospheres followed by annealing treatment. In this approach, PS/ZnS colloidal nanospheres were prepared and then self-assembled into a closely packed PS/ZnS nanofilm at a hexane-water'' interface. By annealing this precursor nanofilm under an optimal condition, a ZnS hollow-sphere nanofilm with a densely packed network structure was obtained. The particle size and morphology of the PS/ZnS colloidal nanospheres and the as-transformed ZnS hollow-spheres were characterized by TEM, HRTEM and SEM. Finally, a UV photodetector was successfully constructed from the as-transformed ZnS hollow-sphere nanofilm.
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