4.3 Article

Evaluation of structure-property relationships of solution-processible fullerene acceptors and their n-channel field-effect transistor performance

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 22, Issue 30, Pages 14976-14981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm32693k

Keywords

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Funding

  1. National Science Foundation [DMR-0120967]
  2. Department of Energy [DE-FC3608GO18024/A000]
  3. Air Force Office of Scientific Research [FA9550-09-1-0426]
  4. Office of Naval Research [N00014-11-1-0300]
  5. World Class University (WCU) through the National Research Foundation of Korea under the Ministry of Education, Science and Technology [R31-21410035]
  6. Boeing Foundation
  7. National Science Council of Taiwan [NSC100-2917-I-564-031]

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A series of fullerene acceptors have been selected for the systematic study of their electron-transporting properties on a standardized field-effect transistor (FET) platform. It was found that small structural alternations, functional patterns, and number of addends on fullerene derivatives strongly affect their mobilities. The measured charge mobilities correlate well with structural features of these materials and provide useful insights into designing better fullerene-based semiconductors for organic electronics.

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