4.3 Article

Enhancement of luminescence intensity in TMPY/perylene co-single crystals

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 21, Issue 44, Pages 17662-17666

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm12977e

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A new molecule, 1,3,6,8-tetramethylpyrene (TMPY), with a similar shape to the luminescent material perylene has been successfully synthesized. The co-crystals with perylene doping have been grown and their crystal structure has been clarified by X-ray analysis. Optical spectra indicate that effective energy transfer has been achieved in the doping systems and the luminescence efficiency has reached as high as 78%. The pure TMPY shows p-type characteristics during the FET operation. The hole mobility is up to 0.26 cm(2) V-1 s(-1).

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