Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 21, Issue 3, Pages 863-868Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm02941f
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Funding
- National Basic Research Program of China [2011CB201600]
- National High Technology Research and Development Program of China [2009AA050603]
- Chinese Academy of Sciences [KGCX2-YW-326]
- National Natural Science Foundation of China [20703046]
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Highly crystallized boron-doped anatase TiO2 nanoparticles are prepared by a facile synthetic route and successfully used as the photoanode of dye-sensitized solar cells (DSCs). We have observed that the boron doping could improve the crystallinity of TiO2. Moreover, the highly crystallized anatase boron-doped TiO2 were analyzed by electron paramagnetic resonance (EPR), X-ray photoelectron spectroscopy (XPS) and UV-vis spectroscopy, and the internal resistances of the boron-doped DSCs were studied by measuring the electrochemical impedance spectra (EIS). The improved photocurrent density of the boron-doped DSCs is due to a significant enhancement of IPCE in the range 370-650nm in comparison with that of the undoped DSC. Meanwhile, the energy-conversion efficiency of the cell based on the B-doped TiO2 electrode is enhanced significantly, by about 9%, compared to that of the undoped DSC. Overall, DSCs based on B-doped electrodes show good stability and remain over 95% of their initial efficiency under visible light soaking for more than 2400 h.
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