Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 21, Issue 5, Pages 1387-1394Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm01652g
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Funding
- Saint-Gobain Recherche Company, France
- Royal Academy of Engineering/EPSRC
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The optical properties of Yb3+ and Ho3+ co-doped Y2BaZnO5, synthesized by solid-state reactions, are investigated in detail. Under 977 nm excitation (similar to 25 x 10(-3) W mm(-2)), bright green upconversion emission is observed. Concentration dependence studies at room temperature show that relatively high infrared to visible upconversion efficiencies are obtained with values up to similar to 2.6%. The results of power dependence studies and temperature-dependent lifetime measurements allow us to determine the dominant upconversion mechanisms in Yb3+: Ho3+ co-doped Y2BaZnO5 oxides. The materials presented in this article constitute new and efficient upconversion phosphors which may find utility in a variety of applications.
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