Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 21, Issue 28, Pages 10261-10264Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm11068c
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Funding
- US Department of Energy [DE-FG36-08GO88008]
- US Department of Defense [DD-N000141110069]
- National Science Foundation (NSF) [DMR-10-06776, CBET-0854979, CHE-10-41300]
- Texas [NHARP 01846]
- Robert A. Welch Foundation [E-1551]
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Electrochemically crosslinked surface-grafted poly(N-vinylcarbazole) (PVK) brushes as hole transport layers (HTLs) on a photovoltaic device have been demonstrated using SI-RAFT polymerization. Comparable performance to PEDOT: PSS/P3HT: PCBM based devices was achieved. A main advantage is strong adhesion to ITO with a possible long-term stability against acid dopants and oxygen.
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