4.3 Review

Titania-based photocatalysts-crystal growth, doping and heterostructuring

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 5, Pages 831-843

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/B909930A

Keywords

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Funding

  1. External Cooperation Program of Chinese Academy of Sciences [GJHZ200815]
  2. Major Basic Research Program, Ministry of Science and Technology China [2009CB220001]
  3. Solar Energy Program of Chinese Academy of Sciences
  4. IMR SYNL-T.S. Ke Research Fellowship
  5. Australian Research Council [DP0666345]
  6. Scientific Research Foundation of East China University of Science and Technology [YD0142125]
  7. Pujiang Talents Programme of Science and Technology Commission of Shanghai Municipality [09PJ1402800]
  8. Australian Research Council [DP0666345] Funding Source: Australian Research Council

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Semiconductor photocatalysts have important applications in renewable energy and environment fields. To overcome the serious drawbacks of low efficiency and narrow light-response range in most stable semiconcluctor photocatalysts, many strategies have been developed in the past decades. This review attempts to provide a comprehensive update and examination of some fundamental issues in titania (TiO2)-based semiconductor photocatalysts, Such as crystal growth, doping and heterostructuring. We focus especially on recent progress in exploring new strategies to design TiO2-based photocatalysts with unique Structures and properties, elucidating the chemical states and distribution of dopants in doped TiO2, designing and fabricating integrated heterostructure. photocatalysts with different charge-carrier transfer pathways, and finally identifying the key factors in determining the photocatalytic efficiency of titania-based photocatalysts.

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