4.3 Article

Nitrogen-doped graphene and its electrochemical applications

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 35, Pages 7491-7496

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm00782j

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Funding

  1. Laboratory Directed Research
  2. Pacific Northwest National Laboratory (PNNL)
  3. China Scholarship Council
  4. ARRA/AFOSR [FA9550-09-1-0523]
  5. ARO MURI [W911NF-04-1-0178]

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Nitrogen-doped graphene (N-graphene) is obtained by exposing graphene to nitrogen plasma. N-graphene exhibits much higher electrocatalytic activity toward oxygen reduction and H2O2 reduction than graphene, and much higher durability and selectivity than the widely-used expensive Pt for oxygen reduction. The excellent electrochemical performance of N-graphene is attributed to nitrogen functional groups and the specific properties of graphene. This indicates that N-graphene is promising for applications in electrochemical energy devices (fuel cells, metal-air batteries) and biosensors.

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