Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 26, Pages 5418-5428Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm00061b
Keywords
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Funding
- Ministry of Education of the Czech Republic [1M6198959201, MSM6198959218]
- Academy of Sciences of the Czech Republic [KAN115600801]
- NIH [NS053454]
- Georgia Cancer Coalition
- Distinguished Cancer Clinicians and Scientists Program
- Southeastern Brain Tumor Foundation
- EmTech Bio, Inc.
- NATIONAL INSTITUTE OF NEUROLOGICAL DISORDERS AND STROKE [K08NS053454] Funding Source: NIH RePORTER
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Magnetic nanocomposites containing iron oxide (maghemite - gamma-Fe2O3) nanoparticles, embedded in a synthetic clay matrix (laponite) were prepared by a new one step chemical route and characterized by TEM, XRD, magnetization measurements, Mossbauer spectroscopy, DLS, and MRI measurements. The synthesis procedure leads to non-stoichiometric gamma-Fe2O3 with a controllable content in the nanocomposite. Magnetic nanoparticles incorporated in the diamagnetic clay matrix exhibit a mean diameter of 13 nm and superparamagnetic behaviour with a high saturation magnetization achievable at low applied magnetic fields. The in-field Mossbauer spectra and ZFC/FC magnetization curves reveal a perfect ferrimagnetic ordering within nanoparticles with negligible spin frustration and interparticle interactions due to the incorporation of maghemite nanoparticles into the nanocrystalline laponite matrix, thus, significantly avoiding their clustering and agglomeration. Magnetic iron oxide nanoparticles embedded in the laponite matrix exhibit strong T-2-weighted MRI contrast. The gamma-Fe2O3/laponite nanocomposite particles have a 200 nm hydrodynamic diameter and form very stable hydrosols and/or hydrogels depending on their concentration in water.
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