4.3 Article

Hierarchical ordered mesoporous carbon from phloroglucinol-glyoxal and its application in capacitive deionization of brackish water

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 39, Pages 8674-8678

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm01911a

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Funding

  1. U.S. DOE Office of Energy Efficiency and Renewable Energy (EERE) [DE-AC05-0096OR22725]
  2. Oak Ridge National Laboratory
  3. Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy

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Templated carbon materials have recently received tremendous attention due to energy storage and separations applications. Hierarchical structures are ideal for increased mass-transport throughout the carbon material. A new ordered mesoporous carbon material has been developed using glyoxal which exhibits a hierarchical structure with pore sizes up to 200 nm. The hierarchical structure arises from the cross linking reagent and not from the standard spinodal decomposition of a secondary solvent. The carbon material was studied for potential application as a capacitive deionization (CDI) electrode for brackish water. Results indicate that the hierarchical structure provides a pathway for faster adsorption kinetics when compared to standard resorcinol-formaldehyde CDI electrodes.

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