4.3 Article

Colloids in liquid crystals: a lattice Boltzmann study

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 46, Pages 10547-10552

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm01824d

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Funding

  1. EPSRC [EP/E030173, EP/E045316]
  2. Royal Society
  3. EPSRC [EP/E030173/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/E030173/1] Funding Source: researchfish

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We propose a hybrid lattice Boltzmann algorithm to simulate the hydrodynamics of colloidal particles inside a liquid crystalline host. To validate our algorithm, we study the static and the microrheology of a colloid in a nematic, with tangential anchoring of the director field at the particle surface, and we confirm theories and experiments showing that the drag force in a nematic is markedly anisotropic. We then apply our method to consider the case of a colloid inside a cholesteric, and with normal anchoring at the surface. We show that by tuning the ratio between particle size and cholesteric pitch it is possible to control the defect configuration around the particle, and to stabilise novel figure-of-eight or highly twisted loops close to the colloid surface.

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