Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 4, Pages 715-722Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b917366h
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Funding
- CAPES
- CNPq
- INCT-CMN
- FAPERGS
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A simple and efficient procedure for the synthesis of a new class of selenoesters 4a and 4b was developed. Polarized-light optical microscopy (POM), differential scanning calorimetry (DSC), and X-ray diffraction showed that the selenoester 4a with a shorter alkyl chain displayed a wide nematic range (Delta T = 110.7 degrees C), while 4b with a longer alkyl chain possesses a rich phase polymorphism: Cr -> SmI -> SmC -> N -> I mesophase sequence during heating cycle and I -> N -> SmC -> SmI -> SmX -> Cr transition on cooling. For 4b, a large temperature range (135.7 degrees C) from crystal to isotropic phase can be observed. In addition, UV-Vis, steady-state fluorescence emission and excitation spectra in solution were also applied in order to characterize their photophysical behaviour. Compounds 4a and 4b are fluorescent in the blue region and present a Stokes shift at around 80 nm and 39 nm in dichloromethane and dioxane, respectively.
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