4.3 Article

A ternary cascade structure enhances the efficiency of polymer solar cells

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 14, Pages 2820-2825

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b918362k

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Funding

  1. National Science Council (NSC), Taiwan [NSC 96-2120-M-002-016, NSC 98-2221-E-001-002]
  2. Academia Sinica research program on Nanoscience and Nanotechnology

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In this study, a novel solution-processed small molecule (TQTFA) for use as an electron donor has been incorporated into organic solar cells based on poly(3-hexylthiophene) (P3HT) and (6,6)-phenyl C71-butyric acid methyl (PC[70]BM). The combination of TQTFA with P3HT and PC[70]BM allows not only a broad absorption but also tuning of the inter energy level leading to a higher short-circuit current (J(SC)) and open-circuit voltage (V-OC). The best performing devices exhibited a power conversion efficiency of 4.50%. The efficiency is increased by almost 15% when compared to the one without TQTFA.

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