4.3 Article

Synthesis of metal sulfide nanomaterials via thermal decomposition of single-source precursors

Journal

JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 32, Pages 6612-6617

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm00439a

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Funding

  1. Office of Science, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, U.S. Department of Energy [DE-AC02-05CH11231]

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In this report, we present a synthetic method for the formation of cuprous sulfide (Cu(2)S) and lead sulfide (PbS) nanomaterials directly on substrates from the thermolysis of single-source precursors. We find that the final morphology and arrangement of the nanomaterials may be controlled through the concentration of the dissolved precursors and choice of solvent. One-dimensional (1-D) morphologies may also be grown onto substrates with the addition of a metal catalyst layer through solution-liquid-solid (SLS) growth. These synthetic techniques may be expanded to other metal sulfide materials.

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