Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 41, Pages 9133-9139Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm01235a
Keywords
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Funding
- National Natural Science Foundation of China [20872121]
- Natural Science Foundation [2009BB4001]
- Fundamental Research Funds for the Central Universities [XDJK2009C011, XDJK2009C178]
- Research Funds for the Doctoral Program of Higher Education of China [20090182120010]
- Southwest University Doctoral Fund [SWUB2008075]
- Southwest University [081063505]
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A novel dual responsive nanomaterial sensitive to both photo-and pH stimuli has been successfully developed. The polymer-based nanoparticles were fabricated from a specially designed photo-and pH-responsive amino-substituted azobenzene monomer, 4-amino-4'-methacrylatylazobenzene (AMAAB), via free radical polymerization with trimethylolpropane trimethacrylate (TRIM) cross-linkers. The trans-cis photoisomerization properties of AMAAB were retained after incorporation into the rigid three-dimensional cross-linked polymer matrix. The TRIM/AMAAB molar ratio significantly influenced the kinetics of the trans-cis photoisomerization. The nanoparticles also possessed good pH-responsive properties. The change in absorbance with media pH was monitored at 402 nm, and a titration type'' curve was obtained with a pK(a) value of 0.61 +/- 0.06. At this transition point, the color of the nanoparticle suspension changed colour from yellow to pink. Thermogravimetric analysis (TGA) indicated that the nanoparticles were thermally stable.
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