Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 20, Issue 1, Pages 173-179Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b915822g
Keywords
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Funding
- Grant-in-Aid for Encouragement of Young Scientists B [18750111]
- Ministry of Education, Culture, Sports, Science and Technology
- Creative Scientific Research of Invention of Conjugated Electronic Structures and Novel Function'' [16GS0209]
- Japan Society for the Promotion of Science
- Grant-in-Aid for Scientific Research (A) of Development of Highly Functional Ion-Conductive Materials Using Nanostructured Liquid Crystals''
- [19205017]
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Aligned self-assembled fibers have been obtained for a phenylbithiophene derivative with a laterally fluorinated phenylene group by the application of electric fields. These fibrous aggregates exhibit photoconductive properties due to the stacking of the pi-conjugated moiety. In contrast, a phenylbithiophene derivative without fluoro substituents forms unaligned fibers under electric fields. The dielectric anisotropy of the fluorinated molecule plays a key role in the alignment of photoconductive fibrous aggregates.
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