Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 19, Issue 28, Pages 4965-4972Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b823506f
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Funding
- NASA
- Welch Foundation [F-1254]
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Layered Li[Li0.2Mn0.54Ni0.13Co0.13]O-2, which is a solid solution between layered Li[Li1/3Mn2/3]O-2 and Li[Ni1/3Mn1/3Co1/3]O-2, has been surface modified by single-layer coating with 2-5 wt.% AlPO4, CoPO4, and Al2O3 and double-layer coating with 2 wt.% AlPO4 or 2 wt.% CoPO4 inner layer and 2-3.5 wt.% Al2O3 outer layer. The samples have been characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), electrochemical impedance spectroscopy (EIS), X-ray photoclectron spectroscopy (XPS), and electrochemical measurements in lithium cells. The double-layer coated samples are found to exhibit lower irreversible capacity loss (C-irr) and higher discharge capacity values than both the pristine and the single-layer coated samples, which are due to the retention of a higher number of oxide ion vacancies in the layered lattice after the first charge. The double-layer coated composite cathodes exhibit C-irr values as low as 26 mAh g(-1) with a high discharge capacity of similar to 300 mAh g(-1), which is two times higher than that achieved with layered LiCoO2. Moreover, the double-layer coated samples exhibit higher rate capabilities than the pristine and single-layer coated samples, which are attributed to the suppression of undesired SEI layers and the fast charge transfer reaction kinetics as indicated by the EIS data.
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