Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 19, Issue 3, Pages 344-349Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b818613h
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Funding
- National Science Foundation [DMR-0547976, DMR-0553719]
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Cornell Center for Materials Research (NSF MRSEC) [DMR-0520404]
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Nonspherical particles of pear-like and spherocylinder shape were organized into diverse two-dimensional (2D) structures, including the orientationally disordered rotator. Dry films with hexagonal, oblique, and centered rectangular symmetry were obtained by using convective assembly to condense and confine the system in a thin meniscus region. Monte Carlo simulations confirmed the transition from fluid to rotator simply as a function of system density and short-bond-length particle morphology.
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