Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 19, Issue 44, Pages 8478-8483Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b912698h
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Funding
- Thailand Research Fund through the Royal Golden Jubilee Ph. D. Program [PHD/ 0197/ 2548)]
- Graduate School- PSU
- Center of Innovation in Chemistry
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Higher-ordered 3D macroporous TiO2-functionalized chitosan scaffolds were prepared by ice segregation induced self-assembly (ISISA), in which homogenous dispersions of 6, 27 or 200 nm sized TiO2 nanoparticles and chitosan cross-linked with glycidoxypropyltrimethoxysilane were unidirectionally frozen at -196 degrees C. Scanning electron microscopy showed that under established optimum conditions the monoliths comprised well-aligned 30-50 mu m sized micro-channels running parallel to the direction of ice growth. The surface morphology of the internal wall structure was influenced by the size of the titania nanoparticles. Scaffolds prepared in the presence of 6 nm sized anatase particles showed featureless walls with concealed/embedded nanoparticles, whereas larger TiO2 particles remained exposed at the surface of the channel walls. Mechanical properties of the composite scaffolds were studied under compressive loads and stress-strain measurements obtained, and the effect of particle size on the elastic properties of the macroporous constructs determined. The hybrid scaffolds were shown to be reusable substrates for the photocatalytic degradation of methylene blue and Orange II dye molecules.
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