Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 19, Issue 32, Pages 5726-5729Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b908707a
Keywords
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Funding
- National Basic Research 973 Program [2006CB806200]
- NSFC/China [50673025]
- Scientific Ministry of China [2008DFA41390]
- Scientific Committee of Shanghai
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A novel gated photochromic compound Nap-Pip-DTE was prepared to mimic a soft gear-shift based on alternative UV/Vis irradiation, protonation/deprotonation and copper (II) ion complexation/dissociation. The fluorescence and absorption spectra were used as output signals. Copper ( II) ion was introduced to mimic the parking (P) state by complexation with two intramolecular piperazine moieties of Nap-Pip-DTE, transforming diarylethene moieties into the photo-inactive parallel form.
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