Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 18, Issue 39, Pages 4692-4697Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b808383e
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Funding
- MEC [CTQ2005-02193/BQU]
- DIUE [2005SGR225]
- Consolider Ingenio [CSD2006-0003]
- ICIQ Foundation
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Long chain carboxylic acids functionalized at the omega position with chiral amino alcohol fragments have been used to stabilize cobalt nanoparticles prepared by thermal decomposition of Co-2(CO)(8). The first examples of chirally modified cobalt nanoparticles have been prepared in this manner and used as magnetically decantable ligands in the Ru-catalyzed asymmetric transfer hydrogenation of ketones.
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