Journal
JOURNAL OF MATERIALS CHEMISTRY
Volume 18, Issue 11, Pages 1196-1203Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b717151j
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Ag nanoparticles (NPs) formed in situ by the photochemical reduction of phosphotungstic acid (H3PW12O40, PTA) under UV-irradiation in polyelectrolyte multilayer nanoreactors composed of poly(ethyleneimine)-silver ions (PEI-Ag+) and PTA fabricated on solid substrates by alternating adsorption, wherein the PTA plays the role of a UV-switchable reducing agent and an assembly reagent. Transmission electron microscopy (TEM) images show the formation of sphere-like silver NPs with sizes smaller than 12 nm in the multilayer films. Atomic force microscopy (AFM) and field emission scanning microscopy (FESEM) imply a film with a rough surface. The UV-vis characteristic absorbances of PTA and Ag NPs increase almost linearly with the number of bilayers, suggesting that the deposition process was regular and highly reproducible from layer to layer. X-Ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy ( FTIR) confirm the incorporation of PEI-Ag and PTA into the films. The multilayer films also exhibit good electrocatalytic activity for the oxidation of uric acid, which may be used in electrochemical biosensors.
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