Synthesis and magnetic properties of prussian blue modified Fe nanoparticles

Fe nanoparticles are prepared using a unique polyol process and modified with Prussian blue (PB) at various concentrations. The presence of PB in the Fe nanoparticles are confirmed from thermal, Fourier transform infrared spectroscopy and electron microscopic analyses. The prussian blue existed on ;the surface of the nanoparticles when the concentration is 200 mu M and in excess with 1000 mu M ;Fe nanoparticles are reduced in size using Pt as nucleating agent and modified with the optimum concentration of PB. The saturation magnetization decreases with the concentration of PB whereas the coercivity is influenced by the size of the Fe nanoparticles. The presence of oxide layer in Fe nanoparticles helps in the surface modification with PB. The Fe nanoparticles of particle size 53 nm modified with 200 mu M of PB showed a saturation magnetization of 110 emu/g. The magnetic properties suggest that the PB modified Fe nanoparticles are better candidates for detoxification applications. (c) 2013 Elsevier B.V. All rights reserved.