Journal
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
Volume 322, Issue 21, Pages 3401-3409Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jmmm.2010.06.036
Keywords
Magnetite; Thermoplastic natural rubber; Microstructure; Magnetic property; Microwave absorbing property
Funding
- Scientific Advancement Fund Allocation (SAGA) [STGL-010-2006]
- Ministry of Science, Technology and Innovation, Malaysia (MOSTI) [03-01-02-SF0059]
Ask authors/readers for more resources
Magnetic and microwave absorbing properties of thermoplastic natural rubber (TPNR) filled magnetite (Fe(3)O(4)) nanocomposites were investigated. The TPNR matrix was prepared from polypropylene (PP), natural rubber (NR) and liquid natural rubber (LNR) in the ratio of 70:20:10 with the LNR as the compatibilizer. TPNR-Fe(3)O(4) nanocomposites with 412 wt% Fe(3)O(4) as filler were prepared via a Thermo Haake internal mixer using a melt-blending method. XRD reveals the presence of cubic spinel structure of Fe(3)O(4) with the lattice parameter of a=8.395 angstrom. TEM micrograph shows that the Fe(3)O(4) nanoparticles are almost spherical with the size ranging 2050 nm. The values of saturation magnetization (M(S)), remanence (M(R)), initial magnetic susceptibility (chi(i)) and initial permeability (mu(i)) increase, while the coercivity (H(C)) decreases with increasing filler content for all compositions. For nanocomposites, the values of the real (epsilon(r)') and imaginary permittivity (epsilon(r)''') and imaginary permeability (mu(r)'') increase, while the value of real permeability (mu(r)') decreases as the filler content increases. The absorption or minimum reflection loss (R(L)) continuously increases and the dip shifts to a lower frequency region with the increasing of both filler content in nanocomposites and the sample thickness. The R(L) is -25.51 dB at 12.65 GHz and the absorbing bandwidth in which the R(L) is less than -10 dB is 2.7 GHz when the filler content is 12 wt% at 9 mm sample thickness. (C) 2010 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available