Core-shell structured iron nanoparticles well dispersed on montmorillonite

Iron nanoparticles have been successfully synthesized using sodium borohydride solution reduction of ferric trichloride hexahydrate in the presence of montmorillonite as an effective protective reagent and support as well. A combination of characterizations reveals the well disperse of these obtained iron nanoparticles supported on the external surface of clay with roughly spherical morphology and mean diameter of 55 nm. The particles are oxidation resistant well with iron core-iron oxide shell structure. The shell thickness of 3 nm remains almost invariable under ambient conditions. Discernable hysteresis loop reveals ferromagnetic behavior of the iron nanoparticles, which make them easy for magnetic separation and potential in some practical applications. (C) 2009 Elsevier B.V. All rights reserved.