4.6 Article

Luminescent properties and logic nature of a crown Schiff base responding to sodium ion and zinc ion

Journal

JOURNAL OF LUMINESCENCE
Volume 145, Issue -, Pages 486-491

Publisher

ELSEVIER
DOI: 10.1016/j.jlumin.2013.08.012

Keywords

Schiff bases; N-salicylidenaniline; 15-crown-5; Fluorescent devices; Logic gate

Categories

Funding

  1. China NSFC [20802013, 21072038]
  2. New Century Excellent Talent Program of Chinese Ministry of Education [NCET-07-0242]
  3. Fundamental Research Funds for the Central Universities [HIT. NSRIF. 2012043]
  4. SKLUWR of HIT [ES201010]
  5. Development Program for Outstanding Young Teachers of HIT [HITQNJS 2009.068]
  6. program of excellent Team in HIT
  7. China Postdoctoral Science Foundation [20080440867]
  8. Heilongjiang Postdoctoral Fund [LBH-Z08199]

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An N-salicylidenaniline (SA), compound 1 with 15-crown-5 moiety, was synthesized. Coordinations with Na+ or/and Zn2+ induced obvious changes in fluorescence spectra. When the solvent changed from ethanol to acetonitrile, compound 1 and its complexes exhibited noticeable fluorosolvatochromism. However, the spectral changes all could express the AND logic function in these two solvents. The changes in fluorescence spectra were interpreted as photoinduced electron transfer (PET) and charge transfer transition (CT) mechanisms. (C) 2013 Elsevier B.V. All rights reserved.

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