Journal
JOURNAL OF LUMINESCENCE
Volume 145, Issue -, Pages 486-491Publisher
ELSEVIER
DOI: 10.1016/j.jlumin.2013.08.012
Keywords
Schiff bases; N-salicylidenaniline; 15-crown-5; Fluorescent devices; Logic gate
Categories
Funding
- China NSFC [20802013, 21072038]
- New Century Excellent Talent Program of Chinese Ministry of Education [NCET-07-0242]
- Fundamental Research Funds for the Central Universities [HIT. NSRIF. 2012043]
- SKLUWR of HIT [ES201010]
- Development Program for Outstanding Young Teachers of HIT [HITQNJS 2009.068]
- program of excellent Team in HIT
- China Postdoctoral Science Foundation [20080440867]
- Heilongjiang Postdoctoral Fund [LBH-Z08199]
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An N-salicylidenaniline (SA), compound 1 with 15-crown-5 moiety, was synthesized. Coordinations with Na+ or/and Zn2+ induced obvious changes in fluorescence spectra. When the solvent changed from ethanol to acetonitrile, compound 1 and its complexes exhibited noticeable fluorosolvatochromism. However, the spectral changes all could express the AND logic function in these two solvents. The changes in fluorescence spectra were interpreted as photoinduced electron transfer (PET) and charge transfer transition (CT) mechanisms. (C) 2013 Elsevier B.V. All rights reserved.
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