Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 23, Issue 1, Pages 81-88Publisher
SPRINGER
DOI: 10.1007/s10904-012-9718-4
Keywords
Organometallic polymer; Fluorescence; Phosphorescence; Energy transfer; DFT computations
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- le Fonds Quebecois de la Recherche sur la Nature et les Technologies (FQRNT)
- Centre d'Etudes des Materiaux Optiques et Photoniques de l'Universite de Sherbrooke (CEMOPUS)
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A polymer ([Pt]-ZnP)(n) (ZnP = bis-meso-(hexahexyltruxene)zinc(II) porphyrin; [Pt] = trans-bis(phenylacetylene)bis(tributylphosphine)platinum(II)) was prepared from bis-meso-(hexahexyltruxene)zinc(II) porphyrin and trans-dichlorobis(tributylphosphine)platinum(II) and exhibits fluorescence and phosphorescence from truxene (Tru) and ZnP, and phosphorescence from [Pt] all at once. Evidence for singlet and triplet energy transfer Tru -> ZnP (slow), [Pt] -> ZnP (fast) is provided indicating inter-chromophore interactions. DFT computations indicate strong MO coupling between [Pt] and ZnP.
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