Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 20, Issue 2, Pages 356-360Publisher
SPRINGER
DOI: 10.1007/s10904-010-9349-6
Keywords
Silver(I); Coordination polymer; Schiff base; Crystal structure; Luminescence
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Funding
- National Natural Science Foundation of China [20701012]
- China Postdoctoral Science Foundation [20090460848]
- Foundation for University Youth Key Teacher of Henan Province
- Province and the Ministry of Henan University [SBGJ090517, SBGJ090703]
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A new Ag(I) coordination polymer [AgL(NO3)] (n) 1 (L = 4-benzoylpyridine hydrazone) has been synthesized and characterized by IR, UV, elemental analysis, thermogravimetry and X-ray crystallography. Ag(I)-atom has a seesaw environment with a set of donors from three N-atoms of three ligands and one O-atom from one NO3 (-) anion. Each ligand is bonded to three silver centers and each silver atom is coordinated by three ligands thereby generating two types of bimetallic metallocyclic unit to form a 1D chain. The 1D chains interact each other giving further rise to a 3D supramolecular network through multiform intermolecular hydrogen bonds. The luminescent properties of the polymer 1 at room temperature were investigated.
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